ON SOME Π-HEDRAL SURF SPACE CLAUDE HOPPER, Omnius
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Diaqua(2,2′-bipyridine-κ2 N,N′)bis(perchlorato-κO)copper(II)
The central CuN(2)O(4) motif of the title compound, [Cu(ClO(4))(2)(C(10)H(8)N(2))(H(2)O)(2)], exhibits a Jahn-Teller-distorted octa-hedral geometry around the metal atom, showing a considerably long Cu-O bond distance of 2.5058 (12) Å towards the second perchlorate group, giving a (4 + 1+1)-type coordination mode. In the crystal, the components are linked via inter-molecular O-H⋯O hydrogen bond...
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